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41.
This paper reviews major findings of the Multidisciplinary Experimental and Modeling Impact Crater Research Network (MEMIN). MEMIN is a consortium, funded from 2009 till 2017 by the German Research Foundation, and is aimed at investigating impact cratering processes by experimental and modeling approaches. The vision of this network has been to comprehensively quantify impact processes by conducting a strictly controlled experimental campaign at the laboratory scale, together with a multidisciplinary analytical approach. Central to MEMIN has been the use of powerful two-stage light-gas accelerators capable of producing impact craters in the decimeter size range in solid rocks that allowed detailed spatial analyses of petrophysical, structural, and geochemical changes in target rocks and ejecta. In addition, explosive setups, membrane-driven diamond anvil cells, as well as laser irradiation and split Hopkinson pressure bar technologies have been used to study the response of minerals and rocks to shock and dynamic loading as well as high-temperature conditions. We used Seeberger sandstone, Taunus quartzite, Carrara marble, and Weibern tuff as major target rock types. In concert with the experiments we conducted mesoscale numerical simulations of shock wave propagation in heterogeneous rocks resolving the complex response of grains and pores to compressive, shear, and tensile loading and macroscale modeling of crater formation and fracturing. Major results comprise (1) projectile–target interaction, (2) various aspects of shock metamorphism with special focus on low shock pressures and effects of target porosity and water saturation, (3) crater morphologies and cratering efficiencies in various nonporous and porous lithologies, (4) in situ target damage, (5) ejecta dynamics, and (6) geophysical survey of experimental craters.  相似文献   
42.
L’aquifère libre de la Chaouia côtière constitue un exemple des aquifères les plus exploités au Maroc. Ce travail est consacré à l’étude des processus de la salinisation des eaux souterraines par l’analyse physico-chimique de 39 puits répartis dans la zone. Deux types de faciès ont été révélés, l’un est chloruré-sodique dans la frange côtière ; l’autre faciès est de type chloruré bicarbonaté-calcique caractérisant les eaux exploitées dans les calcaires marneux du Crétacé. L’influence marine (aérosols et intrusion marine), la dissolution/précipitation de la roche aquifère et l’infiltration des eaux d’irrigation, sont parmi les causes de l’augmentation de la salinité des eaux souterraines, en plus de l’exploitation excessive de l’eau souterraine.  相似文献   
43.
The effects of food web structure on the quantity and biochemical composition of seston, zooplankton and recently deposited sediment in experimental freshwater mesocosms were examined. Food web structure was manipulated by addition of zooplanktivorous fish. Biochemical characterisations were carried out using lipid biomarkers (sterols, fatty acids, chlorophyll-derived compounds and long-chain alkanediols). Fish addition decreased zooplankton biomass and increased seston biomass and deposited sediment through a trophic cascade. Fish presence strongly influenced the biochemical characteristics of seston and sediment. In contrast, food web structure had a minor impact on the lipid biomarker composition of zooplankton. Although the relative abundance of sterols in the different compartments did not differ strongly between treatments, sterol profiles in seston and sediment depended on food web structure. The predominance of Δ7-sterols in seston and sediment in the fish treatment indicated a major contribution of Chlorophyceae. In contrast, the distribution of sterols in seston and sediment in the fishless treatment, dominated by cholesterol, indicated a major zooplanktonic input. The distribution of fatty acids and the relative abundance of chlorophyll-derived compounds and long-chain alkanediols agreed with the predominant contribution of phytoplankton or zooplankton to seston and sediment in the two treatments. The relative abundance of bacterial biomarkers suggested that the contribution of bacteria was rather low. The high relative abundance of polyunsaturated fatty acids (PUFAs) and the absence of stanols in sediments suggested low microbial reworking of organic matter in the recently accumulated sediments. The trophic cascade, generated by the addition of fish, increased the relative abundance of PUFAs in deposited organic matter, thus enhancing sediment quality and potential degradability.  相似文献   
44.
Diffusion profiles in minerals are increasingly used to determine the duration of geological events. For this purpose, the distinction between growth and diffusion zoning is critical; it requires the understanding of complex features associated with multicomponent diffusion. Seed-overgrowth interdiffusion experiments carried out in the range 1,050–1,250°C at 1.3 GPa have been designed to quantify and better understand Fe–Mg–Ca interdiffusion in garnet. Some of the diffusion profiles measured by analytical transmission electron microscope show characteristic features of multicomponent diffusion such as uphill diffusion, chemical solitary waves, zero-flux planes and complex diffusion paths. We implemented three different methods to calculate the interdiffusion coefficients of the D matrix from the experimental penetration curves and determined that with Ca as the dependent component, the crossed coefficients of the D matrix are negative. Experiments and numerical simulations indicate that: (1) uphill diffusion in garnet can be observed indifferently on the three components Fe, Mg and Ca, (2) it takes the form of complementary depletion/repletion waves and (3) chemical waves occur preferentially on initially flat concentration profiles. Derived D matrices are used to simulate the fate of chemical waves in time, in finite crystals. These examples show that the flow of atoms in multicomponent systems is not necessarily unidirectional for all components; it can change both in space along the diffusion profile and in time. Moving zero-flux planes in finite crystals are transitory features that allow flux reversals of atoms in the diffusion zone. Interdiffusion coefficients of the D matrices are also analyzed in terms of eigenvalues and eigenvectors. This analysis and the experimental results show that depending on the composition of the diffusion couple, (1) the shape of chemical waves and diffusion paths changes; (2) the width of the diffusion zone for each component may or may not be identical; and (3) the width of diffusion calculated at a given D and duration may greatly vary. D matrices were retrieved from thirteen sets of diffusion profiles. Data were cast in Arrhenius relations. Linear regressions of the data yield activation energies equal to 368, 148, 394, 152 kJ mol−1 at 1 bar and frequency factors Do equal to 2.37 × 10−6, −4.46 × 10−16, −1.31 × 10−5, 9.85 × 10−15 m2 s−1 for [(D)\tilde]FeFeCa \tilde{D}_{FeFe}^{Ca} , [(D)\tilde]FeMgCa \tilde{D}_{FeMg}^{Ca} , [(D)\tilde]MgFeCa \tilde{D}_{MgFe}^{Ca} , [(D)\tilde]MgMgCa \tilde{D}_{MgMg}^{Ca} , respectively. These values can be used to calculate interdiffusion coefficients in Fe–Mg–Ca garnets and determine the duration of geological events in high temperature metamorphic or magmatic garnets.  相似文献   
45.
Tomcod (Microgadus tomcod) in the St. Lawrence estuarine transition zone (ETZ) undergo an ontogenetic habitat shift. Older age classes, characterised by a male-dominated sex ratio, disperse downstream over the summer months to occupy the colder more saline waters of the estuary. Significant differences in length and mass along the salinity gradient were observed in September with upstream fish of any given age class generally exhibiting greater growth. These differences were not seen in early summer. Benthic amphipod δ 34S signatures were strongly correlated with salinity and served to demonstrate that tomcod δ 34S signatures were not in isotopic equilibrium in the more saline waters of the ETZ. Seasonal distributional patterns, growth dynamics and isotopic disequilibrium all indicate that the observed habitat shift may occur on an annual basis, following winter aggregation in warmer, less saline waters. Tomcod located in the downstream parts of the ETZ, predominantly males, were significantly more sexually developed than upstream tomcod for a given age. On the other hand, greater growth early in life is insured by occupying warmer, upstream waters during the summer months.  相似文献   
46.
47.
Travertine deposits in western Turkey are very well‐exposed in the area of Kocaba?, in the eastern part of the Denizli Basin. The palaeoclimatic significance of these travertines is discussed using U/Th dates, stable isotope data and palynological evidence. The Kocaba? travertine occurrences are characterized by successions of depositional terraces associated with palaeosols and karstic features. The travertines have been classified into eight lithotypes and one erosional horizon, namely: laminated, coated bubble, reed, paper‐thin raft, intraclasts, micritic travertine with gastropods, extra‐formational pebbles and a palaeosol layer. The analysed travertines mostly formed between 181 ka and 80 ka (Middle to Late Pleistocene) during a series of climatic changes including glacial and interglacial intervals; their δ13C and δ18O values indicate that the depositional waters were mainly of basinal thermal origin, occasionally mixed with surficial meteoric water. Palynological results obtained from the palaeosols showed an abundance of non‐arboreal percentage and xerophytic plants (Oleaceae and Quercus evergreen type) indicating that a drought occurred. Marine Isotope Stage 6 is represented by grassland species but Marine Isotope Stage 5 is represented by Pinaceae–Pinus and Abies, Quercus and Oleaceae. Uranium/thorium analyses of the Kocaba? travertines show that deposition began in Marine Isotope Stage 6 (glacial) and continued to Marine Isotope Stage 4 (glacial), but mostly occurred in Marine Isotope Stage 5 (interglacial). The travertine deposition continued to ca 80 ka in the south‐west of the study area, in one particular depression depositional system. Palaeoenvironmental indicators suggest that the travertine depositional evolution was probably controlled by fault‐related movements that influenced groundwater flow. Good correlation of the stable isotope values and dates of deposition of the travertines and palynological data of palaeosols in the Kocaba? travertines serve as a starting point for further palaeoclimate studies in south‐west Turkey. Additionally, the study can be compared with other regional palaeoclimate archives.  相似文献   
48.
Abstract

Carbonyl sulphide (OCS) is an important precursor of sulphate aerosols and consequently a key species in stratospheric ozone depletion. The SPectromètre InfraRouge d'Absorption à Lasers Embarqués (SPIRALE) and shortwave infrared (SWIR) balloon-borne instruments have flown in the tropics and in the polar Arctic, and ground-based measurements have been performed by the Qualité de l'Air (QualAir) Fourier Transform Spectrometer in Paris. Partial and total columns and vertical profiles have been obtained to study OCS variability with altitude, latitude, and season. The annual total column variation in Paris reveals a seasonal variation with a maximum in April–June and a minimum in November–January. Total column measurements above Paris and from SWIR balloon-borne instrument are compared with several MkIV measurements, several Network for the Detection of Atmospheric Composition Change (NDACC) stations, aircraft, ship, and balloon measurements to highlight the OCS total column decrease from tropical to polar latitudes. OCS high-resolution in situ vertical profiles have been measured for the first time in the altitude range between 14 and 30?km at tropical and polar latitudes. OCS profiles are compared with Atmospheric Chemistry Experiment (ACE) satellite measurements and show good agreement. Using the correlation between OCS and N2O from SPIRALE, the OCS stratospheric lifetime has been accurately determined. We find a stratospheric lifetime of 68?±?20 years at polar latitudes and 58?±?14 years at tropical latitudes leading to a global stratospheric sink of 49?±?14?Gg?S?y?1.  相似文献   
49.
Murchison Bay is a shallow embayment in the north-western part of Lake Victoria, strongly influenced by urban pollution from the Ugandan capital Kampala. Two stations, representing the semi-enclosed innermost part of the bay and the wider outer part of the bay, were sampled in the period from April 2003 to March 2004, in order to assess the phytoplankton community and the nutrient status in the bay. Murchison Bay was highly eutrophic with average concentrations (n=25) of total phosphorous >90 μg L−1 and total nitrogen >1100 μg L−1 in the inner part of the bay. The phytoplankton community was dominated by a variety of cyanobacterial species and diatoms. Cyanobacteria were dominant in the whole bay, whereas diatoms were more abundant in the outer part of the bay. Moreover, the proportion of N-fixing species like Anabaena sp. was higher in the outer part of the bay, whereas species like Microcystis sp. were more abundant in the inner part of the bay. The phytoplankton community, especially in the outer part of the bay, may be influenced by light limitation. Low NO3-N concentrations in the bay may also indicate a possible N-limitation, thus favouring growth of N-fixing cyanobacteria. The open bay is, however, a complex system, and additional environmental factors and loss processes most likely affect the phytoplankton community.  相似文献   
50.
In climatology and hydrology, univariate Extreme Value Theory has become a powerful tool to model the distribution of extreme events. The Generalized Pareto Distribution (GPD) is routinely applied to model excesses in space or time by letting the two GPD parameters depend on appropriate covariates. Two possible pitfalls of this strategy are the modeling and the interpretation of the scale and shape GPD parameters estimates which are often and incorrectly viewed as independent variables. In this note we first recall a statistical technique that makes the GPD estimates less correlated within a Maximum Likelihood (ML) estimation approach. In a second step we propose novel reparametrizations for two method-of-moments particularly popular in hydrology: the Probability Weighted Moment (PWM) method and its generalized version (GPWM). Finally these three inference methods (ML, PWM and GPWM) are compared and discussed with respect to the issue of correlations.  相似文献   
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